Benzylic C–H addition of aromatic amines to alkenes using a scandium catalyst.

Autor: Su, Jianhong, Luo, Yuncong, Xu, Xin
Předmět:
Zdroj: Chemical Communications; 4/18/2021, Vol. 57 Issue 30, p3688-3691, 4p
Abstrakt: An efficient and selective benzylic C(sp3)–H addition of o-CH3-substituted tertiary aromatic amines to alkenes has been achieved using an anilido-oxazoline ligand supported scandium catalyst, which provides an atom-economic method for the synthesis of a new family of alkylated tertiary anilines. A wide range of amine and alkene substrates are compatible with the catalyst system. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index