Zero-valent ML2 complexes of group 10 metals supported by terphenyl phosphanes.

Autor: Martín, M. Trinidad, Marín, Mario, Rama, Raquel J., Álvarez, Eleuterio, Maya, Celia, Molina, Francisco, Nicasio, M. Carmen
Předmět:
Zdroj: Chemical Communications; 3/28/2021, Vol. 57 Issue 25, p3083-3086, 4p
Abstrakt: Bulky terphenyl phosphane ligands PMe2Ar′ (Ar′ = terphenyl group) facilitate the isolation of zero-valent bis-phosphane complexes of nickel, palladium and platinum. The former show coordination numbers greater than two in the solid state due to the existence of Ni–Carene interactions with the terphenyl fragment. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index