| Autor: |
Jung, Jochen, Münch, Annika, Herbst‐Irmer, Regine, Stalke, Dietmar |
| Předmět: |
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| Zdroj: |
Angewandte Chemie International Edition; 3/8/2021, Vol. 60 Issue 11, p5679-5682, 4p |
| Abstrakt: |
The valence isoelectronic imido analog H2S(NtBu)4 (1) of sulfuric acid H2SO4 was synthesized, isolated, and characterized by NMR spectroscopy and high‐resolution X‐ray charge density analysis. The latter reveals strongly polarized Sδ+−Nδ− bonds with virtually no double bond character. The easy‐to‐polarize S−N bonds are an advantageous and versatile feature of sulfur nitrogen ligands, which enables them to adapt to different electron requirements of various metal cations. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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