Guest Inclusion of Pyridine Molecules into a Copper (II)-Bilayer Hydrogen-Bonded Metal–Organic Framework.

Autor:	Nguyen, Hoan H., Hogan, Christina E., Hogan, Greg A.
Předmět:	METAL-organic frameworks PYRIDINE X-ray crystallography ETHANOL MOLECULES CUCURBITURIL
Zdroj:	Journal of Chemical Crystallography; Mar2021, Vol. 51 Issue 1, p82-87, 6p
Abstrakt:	In this study, the continued investigation of a copper (II) complex that yields an extended hydrogen-bonded bilayer framework and it's ability to include guest molecules, particularly pyridine molecules. Our previous study has shown the ability of this framework to include long-chanined alkyl alcohol molecules and now the copper-based framework has the ability to include pyridine molecules, via non-coordinative and coordinative inclusion. The description of three guest included hydrogen-bonded frameworks that will be discussed: (1) [α-methylbenzylammonium]2Cu(PDCA)2(H2O)·(pyridine), (2) [α-methylbenzylammonium]2Cu(PDCA)2(H2O)·(4-methylpyridine), (3) [α-methylbenzylammonium]2Cu(PDCA)2(H2O)·(4-tert-butylpyridine). The guest included frameworks will be discussed based on X-ray crystallography structures and thermogravimetric analysis data. The creation of a hydrogen-bonded metal-organic bilayer framework that allows for coordinative and non-coordinative guest inclusion of pyridine and pyridine derivatives. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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