| Autor: |
Bertrand, Guillaume H. V., Hamel, Matthieu, Dumazert, Jonathan, Coulon, Romain, Frangville, Camille |
| Předmět: |
|
| Zdroj: |
Polymers for Advanced Technologies; Feb2021, Vol. 32 Issue 2, p748-754, 7p |
| Abstrakt: |
Taking advantage of lanthanide chemistry and coordination dynamics, a method was elaborated to embed high amounts of organometallic complexes inside a polymeric matrix. The use of a carbonylated cross‐linker allows more than a 10‐fold increase of the solubility in monomeric solution, which can afford samples reaching up to 1 wt% incorporation of lanthanides atoms. Derivatives of these samples were used as plastic scintillators to observe total gamma‐ray absorption (Photoelectric [PE] effect) of a 241Am source. The analysis was conducted on the PE occurrence rate, which showed a discontinuity along the lanthanide row, confirming that the observed signal is indeed due to PE events. These methods also provide mechanically durable samples with stable photophysical properties comparable to a solution study of lanthanides complexes. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
Plný text