| Autor: |
Arata, Shogo, Suzuki, Kosuke, Yamaguchi, Kazuya, Sunada, Yusuke |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 12/28/2020, Vol. 49 Issue 48, p17537-17541, 5p |
| Abstrakt: |
Supersilyl, –Si(SiMe3)3, serves as an effective ligand to afford a series of four-coordinate manganese(II) complexes. A dinuclear complex, [(THF)Mn{Si(SiMe3)3}(μ-Br)]2 (2), was readily synthesized by the reaction of MnBr2 with KSi(SiMe3)3. A subsequent ligand exchange of Br in 2 to –OtBu, methyl, or hydride afforded the corresponding manganese(II) complexes. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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