Autor: |
Koohgard, Mehdi, Karimitabar, Haniehsadat, Hosseini-Sarvari, Mona |
Předmět: |
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Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 12/21/2020, Vol. 49 Issue 47, p17147-17151, 5p |
Abstrakt: |
The combination of black TiO2 nanoparticles (NPs) with a nickel catalyst provides a low-cost, sustainable, and reusable alternative dual catalytic system to a homogeneous counterpart (noble metals). This black TiO2-photoredox/nickel dual catalytic system has efficiently driven C–P bond formation between aryl iodides and diarylphosphine oxides under visible light, providing good to excellent yields as well as tolerating a variety of functional groups. The practical application of this semi-heterogeneous protocol has been highlighted by a sunlight experiment, a gram-scale reaction, and a reusability test. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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