Autor: |
Ning, Shu-yu, Yang, Xinyu, Wang, Yan, Zhu, Zhongwen, Zhang, Jiuxing |
Předmět: |
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Zdroj: |
CrystEngComm; 12/21/2020, Vol. 22 Issue 47, p8236-8242, 7p |
Abstrakt: |
A high-quality and large-sized GdB6 single crystal was successfully prepared by using the optical floating zone method to accurately control the temperature and composition of the molten zone. A GdB6 [100] single crystal 25 mm in length and 5 mm in diameter was obtained. The full width at half-maximum (FWHM) of the X-ray rocking curves was 0.227°, which indicated that the as-grown GdB6 single crystal had a high quality. The maximum thermionic emission current density of the GdB6 single crystal was 6.73 A cm−2 at U = 4000 V and T = 1873 K, and the average work function was 2.99 eV. Combining first-principles calculations and experiments, the work function was found to monotonically increase as the size of the GdB6 single crystal changed from nanostructure (1D) to bulk (3D). [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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