| Autor: |
Pilicode, Naveenchandra, Naik, Praveen, Nimith, K. M., Acharya, Madhukara, Satyanarayan, M. N., Adhikari, Airody Vasudeva |
| Předmět: |
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| Zdroj: |
Polymers for Advanced Technologies; Jan2021, Vol. 32 Issue 1, p131-141, 11p |
| Abstrakt: |
Four new Schiff‐base type conjugative polymers (CPs), that is, Py1‐4 carrying a strong electron‐withdrawing cyanopyridine scaffold coupled with different electron‐donating aromatic/heteroaromatic moieties were synthesized from their respective co‐monomers by simple poly‐condensation route. They were subjected to structural, thermal, photophysical, and electrochemical characterizations and theoretical investigations in order to identify their suitability in polymer light‐emitting diode (PLED) application. All these polymers showed good film‐forming ability and exhibited favorable photophysical behaviors with an optical bandgap in the order of 2.54‐2.68 eV. Further, their electrochemical data were used to evaluate highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels. Finally, Py1‐4 were successfully employed as blue‐light emitter in the construction of new ITO/PEDOT:PSS/ Py1‐4/Al configured light‐emitting diodes (LED), and the fabricated devices demonstrated stable blue electroluminescence behavior endorsing an effective electrons injection in the PLEDs. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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