Long-range order in a multilayer organic film templated by a molecular-induced surface reconstruction: Pentacene on Au(110).

Autor: Guaino, Ph., Carty, D., Hughes, G., McDonald, O., Cafolla, A. A.
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Zdroj: Applied Physics Letters; 10/4/2004, Vol. 85 Issue 14, p2777-2779, 3p, 2 Diagrams
Abstrakt: We describe the growth of a highly ordered pentacene film on the Au(110) surface, investigated in both real and reciprocal space using scanning tunneling microscopy and low-energy electron diffraction techniques. At high coverage, a unidirectional multilayer of π-stacked molecular row is formed with long-range order. Investigations of the interface at low molecular coverage show that this molecular arrangement is a direct consequence of a pentacene-induced surface reconstruction. Pentacene molecules initially adsorb between atomic gold rows of the Au(110)–(1×2) missing row structure and induce a (1×3) surface reconstruction, acting as a template for the organic film formation. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index