A study of fluorine-containing catalysts based on MOR and BEA zeolites in isomerization of n-hexane.

Autor: Dzhikiya, O. V., Smolikov, M. D., Belopukhov, E. A., Yablokova, S. S., Doronin, A. O., Gulyaeva, T. I., Muromtsev, I. V., Belyi, A. S., Myshlyavtsev, Alexander V, Likholobov, Vladimir A, Yusha, Vladimir L
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Zdroj: AIP Conference Proceedings; 2020, Vol. 2285 Issue 1, p1-8, 8p
Abstrakt: The effect of fluorine introduction into the catalysts based on beta and mordenite-type zeolites on their textural, structural and acidic properties and catalytic performance in isomerization of n-hexane was studied. The introduction of fluorine was shown to decrease the amount of acid sites detected by ammonia TPD in the temperature range of 100-500 °C. It was found that fluorine-containing catalysts based on beta and mordenite zeolites are more selective toward the formation of mono- and dimethyl-substituted isomers of hexane and provide a higher yield of C5+ hydrocarbons as compared to undoped systems. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index