Autor: |
El Aoufir, Y., Sebhaoui, J., Lgaz, H., El Bakri, Y., Guenbour, A., Bentiss, F., Zarrouk, A., Essassi, E.M., Oudda, H. |
Předmět: |
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Zdroj: |
Protection of Metals & Physical Chemistry of Surfaces; 2020, Vol. 56 Issue 5, p1027-1038, 12p |
Abstrakt: |
The inhibiting effect of benzimidazole derivate (DBI) on corrosion of carbon steel (CS) at temperature range of 303–333 K was investigated in hydrochloric acid by DC potential dynamic polarization and AC electrochemical impedance spectroscopy. It was found that this compound behaved as a mixed-type inhibitor with predominantly cathodic effect. The EIS results indicate that the inhibition efficiency increases with increasing the inhibitor concentration and the maximum inhibition (%) was obtained in the presence of 10−3 M of DBI. The adsorption of DBI on the carbon steel surface is described by the Langmuir adsorption isotherm and had a physical and chemical mechanism. The results found experimentally were corroborated by DFT-quantum chemical calculations and molecular dynamics simulations (MDS) methods. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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