| Autor: |
Shoshani, Manar M., Agapie, Theodor |
| Předmět: |
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| Zdroj: |
Chemical Communications; 9/28/2020, Vol. 56 Issue 76, p11279-11282, 4p |
| Abstrakt: |
A new multidentate tetraanionic ligand platform for supporting trinuclear transition metal clusters has been developed. Two trisphenoxide phosphinimide ligands bind three Ni centers in a triangular arrangement. The phosphinimide donors bridge in μ3 fashion and the phenoxides complete a pseudo-square planar coordination sphere around each metal center. Electrochemical studies reveal two pseudo-reversible oxidation events at notably low potentials (−0.80 V and +0.05 V). The one electron oxidized species was characterized structurally, and it is assigned as a NiIII-containing cluster. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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