Structure of C15-, C17- and C19-mono-acid β-triacylglycerols.

Autor: Helmholdt, Robert B., Peschar, René, Schenk, Henk
Předmět:
Zdroj: Acta Crystallographica: Section B (Wiley-Blackwell); Feb2002, Vol. 58 Issue 1, p134-139, 6p, 2 Diagrams, 7 Charts, 6 Graphs
Abstrakt: The crystal structures of β-1,2,3-tris(pentadecanoyl)glyceroI (β-C15C15C15), β-1,2,3-tris(heptadecanoy1)glycerol (β-C17C17C17) and β-1,2,3-tris(nonadecanoyl)glycerol (β-C19C19C19) have been determined from high-resolution X- ray powder diffraction data. Grid search and Rietveld refinement have been used to determine and refine the structures, respectively. As in β-1,2,3-tris(tridecanoyl)glycerol (β-C13C13C13) and the even-numbered mono-acid triacylglycerols, all three odd-numbered monoacid triacylglycerols crystallize in space group P¯1; with Z = 2 in an asymmetric tuning-fork conformation and have a lateral acyl chain packing resulting in a layered structure. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index