| Autor: |
Ghosh, Santanu, Das, Sayantani, Kanta De, Chandra, Yepes, Diana, Neese, Frank, Bistoni, Giovanni, Leutzsch, Markus, List, Benjamin |
| Předmět: |
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| Zdroj: |
Angewandte Chemie International Edition; 7/20/2020, Vol. 59 Issue 30, p12347-12351, 5p |
| Abstrakt: |
We describe a highly enantioselective Diels–Alder reaction of cross‐conjugated cyclohexadienones with cyclo-pentadiene, in which five stereocenters are effectively controlled by a strongly acidic and confined imidodiphosphorimidate catalyst. Our approach provides tricyclic products in excellent stereoselectivity. We also report methods to convert the obtained products into useful intermediates and a computational study that aids in gaining deeper insight into the reaction mechanism and origin of stereoselectivity. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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