| Autor: |
Hu, Gongfang, Jiang, Jianbing "Jimmy", Kelly, H. Ray, Matula, Adam J., Wu, Yueshen, Romano, Neyen, Mercado, Brandon Q., Wang, Hailiang, Batista, Victor S., Crabtree, Robert H., Brudvig, Gary W. |
| Předmět: |
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| Zdroj: |
Chemical Communications; 8/18/2020, Vol. 56 Issue 64, p9126-9129, 4p |
| Abstrakt: |
Here, we report the quantitative electroreduction of CO2 to CO by a PNP-pincer iridium(I) complex bearing amino linkers in DMF/water. The electrocatalytic properties greatly depend on the choice of linker within the ligand. The complex 3-N is far superior to the analogues with methylene and oxygen linkers, showing higher activity and better selectivity for CO2 over proton reduction. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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