Ftir and Raman Spectroscopic Study of a Complex Perovskite: Ca0.91-XCe0.09Rb0.04Csx[(Zr0.50Ti0.45)Al0.05]O3, X=0.2 to 0.4, Dedicated for Radioactive Waste Confinement.

Autor: Hasnat, K., Kamel, N., Moudir, D., Mouheb, Y., Kamariz, S., Arabi, A.
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Zdroj: Advances in Materials Science; Jun2020, Vol. 20 Issue 2, p81-94, 14p
Abstrakt: Perovskite is able to sequester simultaneously, in its structure, both actinides and alkaline-earth elements. This study is an attempt to synthesize a complex perovskite Ca0.91-xCe0.09Rb0.04Csx[(Zr0.50Ti0.45)Al0.05]O3 (0.2≤x≤0.4), doped in the same time, with Ce, Cs and Rb. The synthesis is conducted by sintering at 1150°C during 16h. XRX analysis confirms the perovskite formation. SEM observations show a less porous microstructure. FTIR analysis reveals TiO6, Ti-O-Ti, Ti-O and Zr-O vibrations. Raman spectroscopy indicates many orthorhombic perovskite active modes, as: Ti-O6 and Ti-O3 torsions, ZrO7, CaO8 vibrations, the totally symmetric oxygen, and the O-octahedron cage rotation. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index