| Autor: |
Chakraborty, Sujaya, Lohar, Somenath, Dhara, Koushik, Ghosh, Raktim, Dam, Somasri, Zangrando, Ennio, Chattopadhyay, Pabitra |
| Předmět: |
|
| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 7/14/2020, Vol. 49 Issue 26, p8991-9001, 11p |
| Abstrakt: |
A newly designed and synthesized half-condensed organic moiety 2-hydroxy-5-methyl-3-[(2-phenylamino-phenylimino)-methyl]-benzaldehyde (HL′) and a Zn2L4 complex sequentially detect Zn2+ and H2PO4− ions as low as 1.13 nM and1.23 μM, respectively. HL′ and a dinuclear Zn(II) complex of in situ generated L− in a solution formulated as Zn2L4 under investigation were characterized by physicochemical and spectroscopic studies along with detailed structural analyses by single-crystal X-ray crystallography. The selectivity and sensitivity of HL′ towards Zn2+ ions and of the Zn2L4 complex towards H2PO4− ions are based on CHEF and via displacement pathways, respectively. Dual sensing of Zn2+ ions and H2PO4−ions in an aqueous medium via "Green-Blue-Green" emission with the reversible transformation of in situ formed HL′ to HL was established by detailed electronic absorption and emission spectroscopic studies. This non-cytotoxic probe (HL′, i.e. produced HL in solution) and Zn2L4 complexes are able to monitor the subcellular distribution changes of Zn2+ and H2PO4− ions, respectively, by fluorescence microscopy using the human semen sample. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
