| Autor: |
Dennis, Francesca M., Robertson, Craig C., Partridge, Benjamin M. |
| Předmět: |
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| Zdroj: |
Synthesis; 2020, Vol. 52 Issue 13, p1903-1914, 12p |
| Abstrakt: |
A nickel catalyst for the allylboration of aldehydes is reported, facilitating the preparation of homoallylic alcohols in high diastereoselectivity. The observed diastereoselectivities and NMR experiments suggest that allylation occurs through a well-defined six-membered transition state, with nickel acting as a Lewis acid. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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