Maleamic Acid as an Organic Anode Material in Lithium-Ion Batteries.

Autor: Atsbeha Kahsay, Berhanemeskel, Wang, Fu-Ming, Hailu, Alem Gebrelibanos, Su, Chia-Hung
Předmět:
Zdroj: Polymers (20734360); May2020, Vol. 12 Issue 5, p1109-1109, 1p, 2 Diagrams, 4 Graphs
Abstrakt: Low-molecular-weight carbonyl-containing compounds are considered beneficial energy storage materials in alkali metal-ion/alkaline earth metal-ion secondary batteries owing to the ease of their synthesis, low cost, rapid kinetics, and high theoretical energy density. This study aims to prepare a novel carbonyl compound containing a maleamic acid (MA) backbone as a material with carbon black to a new MA anode electrode for a lithium-ion battery. MA was subjected to attenuated total reflection-Fourier-transform infrared spectroscopy, and its morphology was assessed through scanning electron microscopy, followed by differential scanning calorimetry to determine its thermal stability. Thereafter, the electrochemical properties of MA were investigated in coin cells (2032-type) containing Li metal as a reference electrode. The MA anode electrode delivered a high reversible capacity of about 685 mAh g−1 in the first cycle and a higher rate capability than that of the pristine carbon black electrode. Energy bandgap analysis, electrochemical impedance, and X-ray photoelectron spectroscopy revealed that MA significantly reduces cell impedance by reforming its chemical structure into new nitrogen-based highly ionic diffusion compounds. This combination of a new MA anode electrode with MA and carbon black can increase the performance of the lithium-ion battery, and MA majorly outweighs transitional carbon black. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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