| Autor: |
Hensienne, Raphaël, Cusson, Jean-Philippe, Chénard, Étienne, Hanessian, Stephen |
| Předmět: |
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| Zdroj: |
Canadian Journal of Chemistry; 2020, Vol. 98 Issue 6, p292-306, 15p |
| Abstrakt: |
The article discusses a study on the synthesis of a series of alkyl and alkenyl p-methoxy arenes with alpha, beta-disubstituted diamino and amino alcohol groups from beta-nitro and beta-azido benzylic alcohols in the presence of AuCl3 as catalyst. Highlights include general protocol for the acetylation of alcohols, mechanistic rationale for syn-diastereoselectivity, and preferred methods toward benzylic substitution. |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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