Nucleophilic phenylation: a remarkable application of alkoxymethyltriphenylphosphonium salts.

Autor: Cheema, Zain Maqsood, Gondal, Humaira Yasmeen, Raza, Abdul Rauf, Abbaskhan, Ahmed
Zdroj: Molecular Diversity; May2020, Vol. 24 Issue 2, p455-462, 8p
Abstrakt: A new application of α-alkoxymethylphosphonium salts in the nucleophilic phenylation of carbonyl compounds is demonstrated. Phenylation of aldehydes, ketones and acyl halides were studied by employing α-alkoxymethyltriphenylphosphonium halides in the presence of lithium hydroxide. New application of α-alkoxymethyltriphenylphosphonium salts. Metal-free, mild and selective phenylation. Easy preparation and handling of the reagent. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index