Physicochemical Characteristics and Catalytic Activity of Composite Materials Based on Mixed Oxides MTiO3/TiO2 (М = Co, Ni) in 1,2-Dihydroxybenzene Photodegradation Reactions in Aqueous Solutions.

Autor: Absalan, Ya., Isaeva, N. Yu., Bratchikova, I. G., Koval'chukova, O. V., Cherednichenko, A. G.
Předmět:
Zdroj: Petroleum Chemistry; May2020, Vol. 60 Issue 5, p557-562, 6p
Abstrakt: Mixed cobalt and nickel oxides MTiO3/TiO2 (M = Co2+, Ni2+) are synthesized. Organometallic complexes of titanium tetrabutylate Ti(OBu)4 with 1,2-dihydroxybenzene and nitrate hydrates of corresponding metals (M) synthesized under conditions of the modified sol-gel process are used as precursors. The synthesized samples are characterized by field-emission scanning electron microscopy, energy-dispersive X-ray analysis, diffuse reflectance spectroscopy, dispersive X-ray radiation analysis, X-ray diffraction, and low-temperature nitrogen adsorption. The photocatalytic activity of the samples is tested in the ultraviolet spectral range (200 nm < λ < 400 nm) in the photodegradation of 1,2-dihydroxybenzene (catechol) in aqueous solutions. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
Nepřihlášeným uživatelům se plný text nezobrazuje