| Autor: |
Kerim, Mansour Dolé, Boyode, Pakoupati, Garrec, Julian, El Kaïm, Laurent |
| Předmět: |
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| Zdroj: |
Synlett; 2020, Vol. 31 Issue 9, p856-860, 5p |
| Abstrakt: |
We report for the first time a metal-free addition of boronic acids to silylnitronates to afford oxime derivatives through aryl transfer on the carbon nitrogen double bond. A reaction mechanism has been proposed in relation with a DFT study on the key aryl transfer. This arylation process is effective for cycloalkenyl nitro derivatives leading to oximes that may be oxidatively converted into 3-arylisoxazole derivatives. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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