Isolation and structural characterisation of rhodium(III) η2-fluoroarene complexes: experimental verification of predicted regioselectivity.

Autor: Gyton, Matthew R., Kynman, Amy E., Leforestier, Baptiste, Gallo, Angelo, Lewandowski, Józef R., Chaplin, Adrian B.
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 5/14/2020, Vol. 49 Issue 18, p5791-5793, 3p
Abstrakt: The isolation and solid-state characterisation of complexes featuring partially coordinated benzene, fluorobenzene and all three isomers of difluorobenzene are described. Supported by a DFT analysis, this well-defined homologous series demonstrates the preference for η2-coordination of fluoroarenes via the HC=CH sites adjacent to a fluorine substituent. [ABSTRACT FROM AUTHOR]
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