Autor: |
Ahmed, Adeeba, Ahmad, Aiman, Ahmad, Musheer, Kalibabchuk, Valentina A. |
Předmět: |
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Zdroj: |
Acta Crystallographica Section E: Crystallographic Communications; May2020, Vol. 76 Issue 5, preceding p728-731, 9p |
Abstrakt: |
The title compound, C22H17NO2·C3H7NO, was synthesized by condensation of an aromatic aldehyde with a secondary amine and subsequent reduction. It was crystallized from a dimethylformamide solution as a monosolvate, C22H17NO2·C3H7NO. The aromatic molecule is non-planar with a dihedral angle between the mean planes of the aniline moiety and the methyl anthracene moiety of 81.36 (8)°. The torsion angle of the Caryl--CH2--NH--Carylbackbone is 175.9 (2)°. The crystal structure exhibits a three-dimensional supramolecular network, resulting from hydrogen-bonding interactions between the carboxylic OH group and the solvent O atom as well as between the amine functionality and the O atom of the carboxylic group and additional C--H…π interactions. Hirshfeld surface analysis was performed to quantify the intermolecular interactions. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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