A porous fluorinated organic [4+4] imine cage showing CO2 and H2 adsorption.

Autor:	Kunde, Tom, Nieland, Esther, Schröder, Hendrik V., Schalley, Christoph A., Schmidt, Bernd M.
Předmět:	GAS absorption & adsorption ADSORPTION (Chemistry) POROUS materials FULLERENES SURFACE area MESOPOROUS materials THERMAL stability FLUOROSURFACTANTS
Zdroj:	Chemical Communications; 5/2/2020, Vol. 56 Issue 35, p4761-4764, 4p
Abstrakt:	We present the synthesis of a porous, organic [4+4] imine cage containing perfluorinated aromatic panels. Gas adsorption experiments show an uptake of 19.0 wt% CO2 (4.2 mmol g−1, 273 K and at 1 bar) and 1.5 wt% H2 (7.5 mmol g−1, 77 K and at 1 bar) for the specific surface area of 536 m2 g−1 of the crystalline material obtained directly from the reaction mixture, combined with an outstanding thermal stability, making it a very interesting porous material suitable for gas adsorption. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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