Synthesis, Characterization, and Structure of a [Cu(phen)2(OTf)]OTf Complex: An Efficient Nitrogen Transfer Pre‐catalyst.

Autor:	Valle, Henry U., Riley, Kathleen M., Russell, Dylan E., Wolgemuth, Daniel K., Voges‐Haupt, C. Flannery, Rogers, T. Alexander, Redd, Shanterell L., Stokes, Sean L., Emerson, Joseph P.
Předmět:	TRANSITION metal ions TRANSITION metal complexes AZIRIDINATION AZIRIDINES
Zdroj:	ChemistrySelect; 5/15/2018, Vol. 3 Issue 18, p5143-5146, 4p
Abstrakt:	Aziridines are valued as important building blocks for the synthesis of a wide range of active compounds. The development of efficient, cost effective catalysts for nitrene transfer reactions to olefins is a continuing area of research in modern chemistry. There are a number of transition metal complexes that are known to catalyse the aziridination of olefins, however most require expensive transition metal ions. Herein we report our efforts to generate aziridines using a copper(II) complex that offers high efficiency at forming aziridines from olefins and N‐transfer agents. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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