Autor: |
Wang, Yao, Ma, Wen-Bin, Guo, Lin, Song, Xiang-Zhu, Tao, Xue-Yu, Guo, Li-Tong, Fan, He-Liang, Liu, Zhang-Sheng, Zhu, Ya-Bo, Wei, Xian-Yong |
Předmět: |
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Zdroj: |
Journal of Materials Science: Materials in Electronics; Apr2020, Vol. 31 Issue 8, p6263-6273, 11p |
Abstrakt: |
Phytic acid-doped copolymers poly(aniline-co-pyrrole) have been synthesized by chemical polymerization for applications of supercapacitors. The results indicate that poly(aniline-co-pyrrole) copolymer delivered a high specific capacitance (639 F g−1) and 62.3% capacitance retention after 1000 cycles at 3 A g−1 in 1 M H2SO4. The good cycle stability was due to increased structural stability by the formation of cross-link between poly(aniline-co-pyrrole) backbones doped by phytic acid. The high capacitance may result from the formation of large specific surface area and effective conducting paths in the copolymer. A symmetrical supercapacitor device based on this copolymer was designed and provided a high energy density (12.2 Wh kg−1 at the power density of 500 W kg−1). Such results indicate that poly(aniline-co-pyrrole) might be a feasible candidate for electrocapacitive material of supercapacitors and this strategy can be extended to fabricate other conducting polymers for supercapacitor applications. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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