Enantiotopic Discrimination by Coordination‐Desymmetrized meso‐Ligands.

Autor: Li, Yutang, Lidskog, Anna, Armengol‐Relats, Helena, Pham, Thanh Huong, Favraud, Antoine, Nicolas, Maxime, Dawaigher, Sami, Xiao, Zeyun, Ma, Dayou, Lindbäck, Emil, Strand, Daniel, Wärnmark, Kenneth
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Zdroj: ChemCatChem; 3/19/2020, Vol. 12 Issue 6, p1575-1579, 5p
Abstrakt: The first examples of enantiopure catalysts that are chiral merely due to coordination of different metal ions at enantiotopic positions of an achiral meso‐ligand are reported. These catalysts exhibit a pseudo‐Cs symmetry and are able to catalyze reactions demanding simultaneous involvement of two catalytic sites. The latter was demonstrated by application in the asymmetric ring‐opening of meso‐epoxides. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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