| Autor: |
Deng, Peimiao, Xie, Weiguang, Fang, Zhiqiang, Ning, Honglong, Liang, Zhihao, Zhang, Xu, Yuan, Weijian, Wang, Yiping, Yao, Rihui, Peng, Junbiao |
| Předmět: |
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| Zdroj: |
CrystEngComm; 3/14/2020, Vol. 22 Issue 10, p1834-1838, 5p |
| Abstrakt: |
The large-sized polycrystalline stannous oxide (SnO) synthesized by a sol–gel method was found to have attractive crystal structural properties and thermo-oxidative stability. The present work describes the thermal stability performance of this large-size polycrystalline material at different temperatures in air. The obtained results showed a systematic oxidation from SnO to stannic oxide (SnO2) in the range of 450–1300 °C and SnO completely oxidized to SnO2 above 900 °C, but it was in a stable state under 450 °C. Other than this, the lattice parameters of SnO and SnO2 also changed slightly at different temperatures. For instance, the lattice parameters of SnO changed from a = b = 3.799 nm and c = 4.841 nm (at room temperature (RT)) to a = b = 3.803 nm and c = 4.838 nm at 300 °C, and the lattice parameters of SnO2 also changed at 600 °C, 700 °C, and 1000 °C. In addition, the present work also explored the effect of oxygen on the crystal surface at RT. The obtained results showed a slow oxidation process from SnO to SnO2 by being in contact with oxygen. Only 6.4% of SnO on the crystal surface was oxidized after one week, which indicated that SnO was a steady-state material. The obtained large-sized polycrystalline SnO, which exhibited excellent thermo-oxidative stability might be a good candidate as a p-type oxide material for photoelectric applications. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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