Janus bis(NHCs) tuned by heteroatom-bridge oxidation states.

Autor: Naz, Nabila Rauf, Schnakenburg, Gregor, Mikeházi, Antal, Kelemen, Zsolt, Nyulászi, László, Boeré, René T., Streubel, Rainer
Předmět:
Zdroj: Chemical Communications; 2/28/2020, Vol. 56 Issue 17, p2646-2649, 4p
Abstrakt: Synthesis of the first tricyclic bis(carbenes) with facially opposed imidazole-2-ylidenes and two linking phosphorus centres in different oxidation states is presented using a modular, high-yield synthetic route. The formation of homo bimetallic coinage metal complexes provides a glimpse on their potential use. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index