Electrochemical synthesis of hydroxy-thioxo-imidazole carboxylates: an experimental and theoretical study.

Autor:	Sbei, Najoua, Said, Ridha Ben, Rahali, Seyfeddine, Beya, Haouas, Al-Ayed, Abdullah S., Al Mogren, Muneerah Mogren, Benkhoud, Mohamed Lamin, Seydou, Mahamadou
Předmět:	CARBOXYLATES THIOUREA DENSITY functional theory CHEMILUMINESCENCE ACETONITRILE
Zdroj:	Journal of Sulfur Chemistry; Apr2020, Vol. 41 Issue 2, p117-129, 13p
Abstrakt:	We report here the facile synthesis of a new series of hydroxy-thioxo-imidazole carboxylates in good yields using the cyanomethyl anion as an electrogenerated base which is formed when dry acetonitrile is electrolyzed at constant current, followed by addition of different thioureas and diazirine-3,3-dicarboxylate. The mechanism of the reaction, NMR shifts and IR are discussed and compared to density functional theory calculations. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.