Silica-coated Fe3O4 magnetic nanoparticles-supported sulfonic acid as a highly active and reusable catalyst in chemoselective deprotection of tert-butyldimethylsilyl (TBDMS) ethers.

Autor:	Hossein Javadi, Sayed, Zareyee, Daryoush, Monfared, Azam, Didehban, Khadijeh, Mirshokraee, Sayed Ahmmad
Předmět:	SULFONIC acids ETHERS CATALYSTS recycling MAGNETIC nanoparticles CATALYTIC activity CATALYSTS DEOXYRIBOZYMES
Zdroj:	Phosphorus, Sulfur & Silicon & the Related Elements; 2020, Vol. 195 Issue 1, p7-12, 6p
Abstrakt:	Anchored propyl sulfonic acid on the surface of silica-coated magnetic nanoparticles (Fe3O4@SiO2@PrSO3H) was successfully employed in the deprotection of TBDMS ethers. The prepared magnetically separable nanocatalyst exhibited efficient catalytic activity with high conversion and selectivity in cleavage of TBDMS ethers. TBDMS ethers are efficiently cleaved to the corresponding hydroxyl compounds in methanol solution containing 2 mol% magnetic nano-catalysts. Good to excellent yields of products, simple work-up and product separation, selective cleavage of TBDMS ethers in the presence of TBDPS ethers, easy recycling of the catalyst with external magnet with no loss in its activity (7 reaction cycles) are important features of this new protocol. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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