UNAM-1: a robust CuI and CuII containing 3D-hydrogen-bonded framework with permanent porosity and reversible SO2 sorption.

Autor:	Domínguez-González, Ricardo, Rojas-León, Irán, Martínez-Ahumada, Eva, Martínez-Otero, Diego, Lara-García, Hugo A., Balmaseda-Era, Jorge, Ibarra, Ilich A., Percástegui, Edmundo G., Jancik, Vojtech
Zdroj:	Journal of Materials Chemistry A; 12/21/2019, Vol. 7 Issue 47, p26812-26817, 6p
Abstrakt:	The construction of hydrogen-bonded frameworks (HBFs) that express permanent porosity and functionality is challenging due to the delicateness of hydrogen bonds. We present UNAM-1, a robust 3D-HBF fully sustained by charge-assisted H-bonds between [CuIICu I12 (HL)12]10− and [Me2NH2]+ units, which displays a surface area of 522 m2 g−1 and reversibly adsorbs SO2 (3.5 mmol g−1). [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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