| Autor: |
Adenot, Aurélien, Char, Joëlle, von Wolff, Niklas, Lefεave;vre, Guillaume, Anthore-Dalion, Lucile, Cantat, Thibault |
| Předmět: |
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| Zdroj: |
Chemical Communications; 11/7/2019, Vol. 55 Issue 86, p12924-12927, 4p |
| Abstrakt: |
A Pd-catalyzed Hiyama cross-coupling reaction using SO2 is described. The use of silicon-based nucleophiles leads to the formation of allyl sulfones under mild conditions with a broad functional group tolerance. Control experiments coupled with DFT calculations shed light on the key steps of the reaction mechanism, revealing the crucial role of a transient sulfinate anion. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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