| Autor: |
Amon, Alfred, Svanidze, Eteri, Ormeci, Alim, König, Marcus, Kasinathan, Deepa, Takegami, Daisuke, Prots, Yurii, Liao, Yen‐Fa, Tsuei, Ku‐Ding, Tjeng, Liu Hao, Leithe‐Jasper, Andreas, Grin, Yuri |
| Předmět: |
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| Zdroj: |
Angewandte Chemie International Edition; 10/28/2019, Vol. 58 Issue 44, p15928-15933, 6p |
| Abstrakt: |
Semiconducting substances form one of the most important families of functional materials. However, semiconductors containing only metals are very rare. The chemical mechanisms behind their ground‐state properties are only partially understood. Our investigations have rather unexpectedly revealed the semiconducting behaviour (band gap of 190 meV) for the intermetallic compound Be5Pt formed at a very low valence‐electron count. Quantum‐chemical analysis shows strong charge transfer from Be to Pt and reveals a three‐dimensional entity of vertex‐condensed empty Be4 tetrahedrons with multi‐atomic cluster bonds interpenetrated by the framework of Pt‐filled vertex‐condensed Be4 tetrahedrons with two‐atomic polar Be−Pt bonds. The combination of strong Coulomb interactions with relativistic effects results in a band gap. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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