Synthesis, Structure, and Luminescence Properties of a {Mo6I8} Complex with (C6F5)2PO2 Ligands.

Autor: Mironova, Alina D., Mikhajlov, Maxim A., Sukhikh, Taisiya S., Brylev, Konstantin A., Gushchin, Artem L., Eltsov, Ilia V., Stass, Dmitri V., Goryunov, Evgeny I., Brel, Valery K., Sokolov, Maxim N.
Předmět:
Zdroj: Zeitschrift für Anorganische und Allgemeine Chemie; 10/14/2019, Vol. 645 Issue 18/19, p1135-1140, 6p
Abstrakt: Reaction of [Mo6I8(CH3COO)6]2– with bis(pentafluorophenyl)phosphinic acid HO(O)P(C6F5)2 yielded a new bright‐red luminescent complex [{Mo6I8}(O2P(C6F5)2)6]2–, isolated as (Bu4N)(H5O2)[{Mo6I8}(O2P(C6F5)2)6]·3(Et2O)·1.5(acetone). It was characterized by X‐ray analysis, CV, ESI‐mass spectrometry, and NMR spectroscopy. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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