A Sound Sequence to Triphenylphosphino Dibromoplatinum(II) Complexes – Solvothermal Preparation of trans‐[PtBr(µ‐Br)(PPh3)]2.

Autor:	Fioco, David, Belli Dell'Amico, Daniela, Labella, Luca, Marchetti, Fabio, Samaritani, Simona
Předmět:	NUCLEAR magnetic resonance spectroscopy X-ray diffraction EXCHANGE reactions
Zdroj:	European Journal of Inorganic Chemistry; 9/30/2019, Vol. 2019 Issue 36, p3970-3974, 5p
Abstrakt:	A sound synthetic procedure for the preparation of trans‐[PtBr(µ‐Br)(PPh3)]2 is described. The species was fully characterized and used to obtain [PtBr2(PPh3)(L)] complexes (L = DMSO, p‐toluidine, pyridine) by a bridge‐splitting reaction. All products were fully characterized by NMR spectroscopy, together with cis‐[PtBr2(PPh3)(NCCH3)], obtained as an intermediate in the synthesis of the dinuclear precursor. Cis‐[PtBr2(PPh3)(NCCH3)] was also studied by X‐ray diffraction. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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