| Abstrakt: |
MoOCl4 reacts with 1-methylimidazole, 4-methylpiperidine and trimethylsilylimidazole (equimolar molar amounts) in solvent CH3CN to provide MoO2Cl4(C3H3N2CH3)[1], MoOCl4(C5H9NHCH3) CH3CN[4] and MoO2Cl2(C3H4N2), [7]. MoOCl4 reacts with twice the moles of 1,4-diaminobutane, 2-methylpyridine, 4-methylpiperidine and 1-methylpyrrolidine in solvent CH3CN to provide: MoOCl4(H2NC4H8NH2)2 [2], MoOCl4(C5H4NCH3), [3], MoOCl4(C5H9NHCH3)2, [5], MoOCl4(C5H9NHCH3)2, [6] and MoO2Cl4(C4H8NCH3)2, [8]. Complexes have been studied by techniques: elemental quantitative analysis, FTIR, ¹H NMR, Mass (LC-MS). [ABSTRACT FROM AUTHOR] |
