Time-dependent in situ measurement of atmospheric corrosion rates of duplex stainless steel wires.

Autor: Örnek, Cem, Léonard, Fabien, McDonald, Samuel A., Prajapati, Anuj, Withers, Philip J., Engelberg, Dirk L.
Předmět:
Zdroj: NPJ Materials Degradation; 12/1/2018, Vol. 2 Issue 1, pN.PAG-N.PAG, 1p
Abstrakt: Corrosion rates of strained grade UNS S32202 (2202) and UNS S32205 (2205) duplex stainless steel wires have been measured, in situ, using time-lapse X-ray computed tomography. Exposures to chloride-containing (MgCl2) atmospheric environments at 50 °C (12–15 M Cl and pH ~5) with different mechanical elastic and elastic/plastic loads were carried out over a period of 21 months. The corrosion rates for grade 2202 increased over time, showing selective dissolution with shallow corrosion sites, coalescing along the surface of the wire. Corrosion rates of grade 2205 decreased over time, showing both selective and pitting corrosion with more localised attack, growing preferentially in depth. The nucleation of stress corrosion cracking was observed in both wires. Stainless steel: Comprehending corrosion The corrosion of two grades of stainless steel has been studied, in situ, under atmospheric exposure conditions. Grade '2205' duplex stainless steel (DSS) has been suggested as a possible container material for the storage of intermediate-level radioactive nuclear waste in the UK because of its high resistance to corrosion and stress corrosion cracking (SCC). Now a team led by D. Engelberg from The University of Manchester, United Kingdom, have used time-lapse X-ray computed tomography to determine the corrosion rates of strained grade '2202' and '2205' DSS wires—over the course of 21 months—that had been exposed to a chloride-containing thin-film electrolyte. They saw that although the corrosion rate of grade 2202 DSS wires increased with time, the corrosion rate for grade 2205 decreased, confirming its superior corrosion resistance. They also observed the nucleation of SCC cracks in both grades of wire and demonstrated that duplex stainless steels can suffer from low-temperature SCC. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index