Brewster angle optical reflection observation of self-limiting nanoparticle monolayer self-assembly at a liquid/liquid interface.

Autor: Hu, Jiayang, Pan, Brady, Makihara, Takuma, Garcia, Roy D. J., Herman, Irving P.
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Zdroj: AIP Advances; Jun2019, Vol. 9 Issue 6, pN.PAG-N.PAG, 6p
Abstrakt: Real-time optical reflection of incident p-polarized light near Brewster's angle shows that after drop-casting iron oxide nanoparticles (NPs) in heptane on top of a diethylene glycol (DEG) liquid substrate, an iron oxide NP layer forms at the DEG/heptane interface, and it self-limits to a monolayer even when there are excess NPs dispersed in the upper heptane phase. Most modes of NP self-assembly do not self-limit growth after the formation of a single monolayer. Observations are compared to a reflection model incorporating the reflectances expected at each interface. An effective medium model of the dielectric constant is used to model the reflectance of the NP layer at the DEG/heptane interface. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index