| Autor: |
Stepacheva, Antonina A., Markova, Mariia E., Gavrilenko, Alexandra V., Sidorov, Alexander I., Kosivtsov, Yury Yu., Sulman, Esther M. |
| Předmět: |
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| Zdroj: |
CET Journal - Chemical Engineering Transactions; 2019, Vol. 74, p469-474, 6p |
| Abstrakt: |
A study of the structure and catalytic properties of the cobalt- and iron-containing catalysts synthesized by the subcritical deposition in the water medium was performed in the current work. The catalyst synthesis was carried out at a temperature of 200 °C and a total pressure of 7.5 MPa using silica as support. The catalytic activity of the synthesized materials was studied in the liquid-phase Fischer-Tropsch synthesis. The study of catalyst structure and composition showed that the use of silica as catalyst support allows the formation of Coand Fe-containing particles consisted of metal oxides. Testing of the synthesized catalysts in liquid phase Fischer-Tropsch synthesis showed that Co-based catalyst allowed the formation of gasoline-range hydrocarbons. It is noteworthy that Co/SiO2 showed higher selectivity towards the formation of linear C5-C8 hydrocarbons. In the case of Fe-containing catalyst, the formation of a significant amount of oxygenates (C3- C4 alcohols) was found. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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