Determining the Potential of a Silver/Silver Chloride Electrode at Different Temperatures.

Autor: Levanov, A. V., Isaikina, O. Ya., Lunin, V. V.
Zdroj: Russian Journal of Physical Chemistry; Apr2019, Vol. 93 Issue 4, p770-773, 4p
Abstrakt: A simple and reliable way of determining the potential of a laboratory silver/silver chloride electrode (SSCE) is proposed, based on measuring the emf of a galvanic cell composed of silver/silver chloride and copper/copper sulfate (copper in a saturated aqueous solution of copper sulfate) electrodes. The standard thermodynamic characteristics of the reduction of a hexacyanoferrate(III) ion to hexacyanoferrate(II) in an aqueous solution are determined using the determined values of the SSCE potential. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index