| Autor: |
Arumugam, Ramar, Shankar, Bhaskaran, Soumya, K. R., Sathiyendiran, Malaichamy |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 6/7/2019, Vol. 48 Issue 21, p7425-7431, 7p |
| Abstrakt: |
Four new flexible ditopic nitrogen donors possessing a xylene spacer and 2-phenylbenzimidazolyl or its derivatives as a coordinating unit and one rigid bis-chelating ligand consisting of two 2-hydroxyphenylbenzimidazolyl motifs and a central phenylene spacer were synthesized and further used with Re2(CO)10 for making a new family of neutral, heteroleptic tetrahedral-shaped supramolecular coordination complexes via a one-pot approach. The new ligands and the complexes were characterized using various analytical and spectroscopic methods. The molecular structures of the complexes were determined using single crystal X-ray diffraction analysis, which reveal that four rhenium cores are arranged in the vertices, and four ligands are at the edges of the tetrahedron. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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