Crystal structure of N-{N-[N-(tert-butoxycarbonyl)-L-α-aspartyl]-L-α-aspartyl}-L-α-aspartic acid 14,24,34-trimethyl ester 3¹-2-oxo-2-phenylethyl ester {Boc-[Asp(OMe)]3-OPac}.

Autor: Takuma Kato, Saki Kishimoto, Akiko Asano, Mitsunobu Doi
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Zdroj: Acta Crystallographica Section E: Crystallographic Communications; May2019, Vol. 75 Issue 5, p585-588, 13p
Abstrakt: In the title homotripeptide {Boc-[Asp(OMe)]3-OPac}, C28H37N3O13, all peptide bonds adopt an s-trans conformation with respect to the N--H and C=O groups. In the crystal, N--H...O hydrogen bonds result in an infinite parallel ß-sheet structure running along the b-axis direction. The Boc protecting group at the N-terminus of the peptide is disordered over two sites with occupancy factors of 0.504 (5) and 0.496 (5). [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index