Crystal structure of 1-heptafluorotolyl-closo-1,2-dicarbadodecaborane.

Autor: Watson, James D., Benton, Amanda, Tricas, Hugo, Rosair, Georgina M., Welch, Alan J.
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications; Apr2019, Vol. 75 Issue 4, Following p512-515, 15p
Abstrakt: The mol­ecular structure of the title compound 1-(2′,3′,5′,6′-tetra­fluoro-4′-trifluoro­methyl­phen­yl)-closo-1,2-dicarbadodeca­borane, C9H11B10F7, features an intra­molecular ortho-F...H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the hepta­fluoro­tolyl substituent in which the plane of the aryl ring nearly eclipses the C1—C2 cage connectivity. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index