Reaction of the C60 radical anion with alkyl halides.

Autor: Maeda, Yutaka, Sanno, Makoto, Morishita, Tatsunari, Sakamoto, Kodai, Sugiyama, Eiichiro, Akita, Saeka, Yamada, Michio, Suzuki, Mitsuaki
Předmět:
Zdroj: New Journal of Chemistry; 5/7/2019, Vol. 43 Issue 17, p6457-6460, 4p
Abstrakt: The reaction of the C60 radical anion (C60) with α-bromo-1,3-dicarbonyl compounds selectively afforded the methanofullerene derivatives. The reaction with benzyl halide and 1,2-bis(dihalomethyl)benzene afforded the corresponding 1,4-dibenzylated C60 derivative and cycloaddition product, respectively. The possible mechanisms for the formation of the fullerene adducts are proposed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index