Heterodinuclear Group 13 Element Complexes of N4O6‐Type Dipyrrin with an Unsymmetrical Twisted Structure.

Autor:	Saikawa, Makoto, Noda, Takumu, Matsuoka, Ryota, Nakamura, Takashi, Nabeshima, Tatsuya
Předmět:	DIPYRRINS COMPLEX compounds SYMMETRY (Physics) MACROCYCLIC compounds CYCLIC compounds X-ray diffraction
Zdroj:	European Journal of Inorganic Chemistry; Feb2019, Vol. 2019 Issue 6, p766-769, 4p
Abstrakt:	Heterodinuclear group 13 element complexes of an N4O6‐type dipyrrin cyclic dimer were synthesized by the stepwise reaction with boron and group 13 elements (Al, Ga, and In). The macrocycles have a new type of unsymmetrical twisted (pseudo‐figure‐of‐eight) structure. Heterodinuclear group 13 element complexes of an N4O6‐type dipyrrin cyclic dimer were synthesized by the stepwise reaction with boron and group 13 elements (Al, Ga, and In). Single crystal X‐ray diffraction analysis revealed the uniquely twisted pseudo‐figure‐of‐eight structures of the unsymmetrical complexes. Photophysical properties of these complexes were also investigated. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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