Esterification of Tertiary Amides by Alcohols Through C−N Bond Cleavage over CeO2.

Autor: Toyao, Takashi, Nurnobi Rashed, Md., Morita, Yoshitsugu, Kamachi, Takashi, Hakim Siddiki, S. M. A., Ali, Md. A., Touchy, Abeda S., Kon, Kenichi, Maeno, Zen, Yoshizawa, Kazunari, Shimizu, Ken‐ichi
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Zdroj: ChemCatChem; 1/9/2019, Vol. 11 Issue 1, p15-15, 1p
Abstrakt: The front cover artwork for our 10th Anniversary Issue is provided by the research groups of Ken‐ichi Shimizu at Hokkaido University and Kazunari Yoshizawa at Kyushu University (Japan). The image shows a C−N bond cleavage reaction catalyzed by CeO2. See the Full Paper itself at https://doi.org/10.1002/cctc.201801098. "Experimental and computational investigations indicate that cooperative effects of acid‐base functions of CeO2 are key for the efficient promotion of alcoholysis reactions of tertiary amides through C−N bond cleavage to form esters." This and more about the story behind the research featured on the front cover can be found in this issue's Cover Profile. Read the full text of the corresponding research at https://doi.org/10.1002/cctc.201801098. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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